Tetrahedron Letters p. 9461 - 9464 (1994)
Update date:2022-08-04
Topics:
Alonso, Ines
Carretero, Juan C.
Ruano, Jose L. Garcia
Cabrejas, Luisa M. Martin
Lopez-Solera, Isabel
Raithby, Paul R.
The reactions of (S)-2-p-tolylsulfinyl-2-cylopentenone with Dane's diene catalyzed by EtAlCl2 yields adducts easily desulfinylated into optically pure perhydro-cyclopentaphenanthrenes.The endo-(controlled by CO group) and regio- (controlled by the subs
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