Aldol equilibrations of unprotected trihydroxybicyclic lactones: Enantiomeric Tetrahydroxy-α-aminocyclopentane carboxylic acids from epimeric bicyclic lactones

DOI: 10.1016/S0040-4039(00)78528-5

Source and publish data:

Tetrahedron Letters p. 8895 - 8898 (1994)

Update date:2022-07-30

Topics:

Authors:

Hui, Andrew

Fairbanks, Antony J.

Nash, Robert J.

Lilley, Paul M. De Q.

Storer, Richard

Watkin, David J.

Fleet, George W. J.

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Article abstract of DOI:10.1016/S0040-4039(00)78528-5

Six stereoisomers - including an enantiomeric pair - of 1-amino-2,3,4,5-tetrahydroxy-cyclopentane-1-carboxylate have been prepared from a single azidolactone starting material by a series of remarkable aldol equilibrations.

Full text of DOI:10.1016/S0040-4039(00)78528-5

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