From aryliodonio-quinoline-8-olates to arylquinolinium-8-olates by a two step aryl migration

DOI: 10.1016/0040-4039(94)02280-O

Source and publish data:

Tetrahedron Letters p. 443 - 446 (1995)

Update date:2022-08-03

Topics:

Authors:

Georgantji, Asimoula

Spyroudis, Spyros

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Article abstract of DOI:10.1016/0040-4039(94)02280-O

The reaction of 4-nitro-8-hydroxyquinoline with (diacetoxyiodo)benzene affords aryliodonio-quinoline-8-olates. Thermal migration of the aryl group from iodine to oxygen and photochemical migration from oxygen to nitrogen leads to the formation of intesively coloured arylquinolinium-8-olates.

Full text of DOI:10.1016/0040-4039(94)02280-O

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