Enantioselective syntheses and resolution of the key White intermediate for the synthesis of trisporic acids

DOI: 10.1016/0957-4166(96)00109-7

Source and publish data:

Tetrahedron Asymmetry p. 1041 - 1057 (1996)

Update date:2022-08-03

Topics:

Authors:

Bacigaluppo, Jose A.

Colombo, Maria I.

Preite, Marcelo D.

Zinczuk, Juan

Ruveda, Edmundo A.

Sieler, Joachim

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Article abstract of DOI:10.1016/0957-4166(96)00109-7

Two asymmetric syntheses of the alkylated cyclohexenone carboxylic acid moiety, the key White intermediate (4a), of trisporic acids A, B and C are described. The syntheses feature a Michael addition in tandem with an aldol condensation as the central step

Full text of DOI:10.1016/0957-4166(96)00109-7

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