Chemical Communications p. 5644 - 5647 (2014)
Update date:2022-07-29
Topics:
Li, Zheng-Zheng
Yao, Su-Yang
Wu, Jin-Ji
Ye, Bao-Hui
The reaction of Δ/Λ-[Ru(bpy)2(py)2] 2+ with a prochiral sulfide ligand, and then in situ oxidation, provide the corresponding Δ-[Ru(bpy)2{(R)-OSO-iPr}]+ and Λ-[Ru(bpy)2{(S)-OSO-iPr}]+ (OSO-iPr = 2-isopropylsulfonylbenzonate) enantiomers in a yield of 83% with 98% ee. The chiral sulfoxides were obtained by treatment of the sulfoxide complexes with TFA in a yield of 90% with 88-91% ee. the Partner Organisations 2014.
Changzhou Jiana Chemical Co.,Ltd
website:http://www.jianachem.com
Contact:86-0519-88731808
Address:Zhenglu Town Wujin City, Jiangsu Province
Taizhou Crene Biotechnology co.ltd
Contact:86-576-88813233 88205808
Address:Economic Developed Zone of Taizhou Zhejiang China
Tianjin Pharmacn Medical Technology Co.,Ltd.
Contact:86-22-60122566ext.866(English),23359620
Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
website:http://www.herbpurify.com
Contact:0086-028-85249238
Address:Room709-C1,Incubator Building, Tianfu Life Science Park No.88,Keyuan Road,Gaoxin district,Chengdu City,Sichuan Prov,China
Contact:86-25-58619180
Address:Nanjing High-Tech Zone 10 Xinghuo Road Pukou District Nanjing, Jiangsu 210061 The People's Republic of China
Doi:10.1016/j.bmcl.2014.04.032
(2014)Doi:10.1055/s-2005-916072
(2005)Doi:10.1016/S0008-6215(00)90633-5
(1986)Doi:10.1016/j.bmcl.2005.09.038
(2006)Doi:10.1021/ja01217a010
(1945)Doi:10.1021/ja01318a042
(1934)
