Exclusive 6-Endo Radical Cyclizations of α-Silyl Radicals Derived From Carbohydrate Allylic Silylethers

DOI: 10.1016/S0040-4039(00)73076-0

Source and publish data:

Tetrahedron Letters p. 3703 - 3706 (1994)

Update date:2022-08-03

Topics:

Authors:

Mayon, P.

Chapleur, Y.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)73076-0

The cyclization of 2-sila-3-oxa-5-hexen-1-yl radicals in conformationaly biased sugar ring systems depends on the stereochemistry of the starting allylic alcohol and proceeds exclusively via the 6-endo mode with a preference for the formation of cis fused

Full text of DOI:10.1016/S0040-4039(00)73076-0

Products guided by the article

Product name:(2R,4aR,6S,8R,8aS)-6-Methoxy-2-phenyl-7-prop-(Z)-ylidene-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

Cas No:161821-24-5

R&D Labs maybe for 161821-24-5

Henan Yellow River New Material Technology Co.Ltd.

website:http://www.yellowriverchem.com

Contact:0086-373-7278760

Address:Chengguan Town, Yuanyang County
Chengdu Green technology Co.,Ltd.

Contact:86-28-82608355

Address:C9 ,Economic Headquarters, Economic Development Zone, Chengdu.
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002

Relevant to this article

Cooperative transition metal/lewis acid bond-activation reactions by a bidentate (boryl)iminomethane complex: A significant metal-borane interaction promoted by a small bite-angle lz chelate

Doi:10.1021/ja505843g
(2014)
Synthesis and structure-activity relationships of 4-fluorophenyl-imidazole p38α MAPK, CK1δ and JAK2 kinase inhibitors

Doi:10.1016/j.bmcl.2014.05.080
(2014)
Pitfalls in bromination reactions of zinc porphyrins: Two-sided ring opening of the porphyrin macrocycle

Doi:10.1021/ic500468r
(2014)
A trinuclear Zn₃(OAc)₄-3,3′-bis(aminoimino) binaphthoxide complex for highly efficient catalytic asymmetric iodolactonization

Doi:10.1039/c4cc02415j
(2014)
Muscle-Mimetic Synergistic Covalent and Supramolecular Polymers: Phototriggered Formation Leads to Mechanical Performance Boost

Doi:10.1021/jacs.0c10918
(2021)
Stepwise π-extension of meso-alkylidenyl porphyrins through sequential 1,3-dipolar cycloaddition and redox reactions

Doi:10.1039/c4cc04283b
(2014)

Article Doi