Chemical and Pharmaceutical Bulletin p. 1148 - 1151 (1991)
Update date:2022-08-05
Topics:
Ishibashi
Mino
Sakata
Inada
Ikeda
Ethyl 3-chloro-3-(3,4-dichlorophenylthio)propanoate (8) reacted with electron-rich arenes in the presence of titanium tetrachloride to give the Friedel-Crafts products 10a-13a. Reactions of 8 with 1-trimethylsilylalkynes 14a-d were effected with aluminum chloride to afford the substitution products 15a-d. Some chemical transformations of the products are also described.
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