Synthesis via a cyclic dioxatrichlorophosphorane of 1,3-dibenzyl-2-phosphonooxy citrate

DOI: 10.1016/S0040-4039(00)76002-3

Source and publish data:

Tetrahedron Letters p. 927 - 930 (1994)

Update date:2022-08-04

Topics:

Authors:

Pankowski, Andrew H.

Meehan, John D.

Sallis, John D.

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Article abstract of DOI:10.1016/S0040-4039(00)76002-3

Phosphorylation of tribenzyl citrate with PCl₅ proceeds via a cyclic dioxatrichlorophosphorane and results in the formation of 1,3-dibenzyl-2-phosphonooxy citrate. A mechanism for the phosphorylation and ester hydrolysis is proposed and the use

Full text of DOI:10.1016/S0040-4039(00)76002-3

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