Tetrahedron p. 12883 - 12894 (1994)
Update date:2022-07-29
Topics:
Tanaka, Shigeyoshi
Tatsuta, Nobuaki
Yamashita, Osamu
Isobe, Minoru
Pyranose ring of cobalt-complexed alkynyl sugars was cleaved by Nicholas reaction.The reaction of 22 was diastereoselective and this selectivity was presumably due to steric interaction between cobalt acetylene moiety and tert-butyldiphenylsilyloxy functi
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