Tetrahedron (2019)
Update date:2022-07-31
Topics:
Zheng, Lin-Chuang
Li, Lin
Duan, Lili
Li, Yue-Ming
A method for regioselective intramolecular sulfenoamination of unactivated terminal olefins was reported. Using sulfonyl hydrazides as the sulfur sources, FeBr3 as the catalyst and (NH4)2S2O8 as the oxidant, different sulfenylmethylpyrrolidines and sulfenylmethylpiperidines were obtained in moderate to high yields via intramolecular sulfenoamination of (sulfon)amidopentenes or (sulfon)amidohexenes.
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