Phenylantimony(III) Dithiocyanate and the Crystal Structure of K

DOI: 10.1039/DT9950001173

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1173 - 1176 (1995)

Update date:2022-08-02

Topics:

Authors:

Forster, Glynis E.

Begley, Michael J.

Sowerby, D. Bryan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950001173

It is not possible to isolate phenylantimony dithiocyanate from phenylantimony dichloride (1 mol) and 2 equivalents of potassium thiocyanate in acetonitrile and a salt, K, is isolated instead.A tetrathiocyanate salt, K2, has also been isolated and K can be obtained from SbPh2(SCN) and K(SCN).In K, X-ray diffraction shows that all the thiocyanate groups are S-bonded and the compound has an unusual polymeric structure in which the sulfur atom of one thiocyanate group bridges between pairs of antimony atoms.Co-ordination about antimony is square pyramidal with an apical phenyl group and sulfur atoms of two terminal (Sb-S 2.573, 2.595 Angstroem) and two cis 1,1-sulfur bridging thiocyanate groups (Sb-S 2.938, 2.999 Angstroem) forming the basal plane.All thiocyanate groups are orientated in the same fashion leading to distorted octahedral co-ordination about potassium.

Full text of DOI:10.1039/DT9950001173

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:potassium diphenylantimony dithiocyanate

Cas No:165333-71-1

R&D Labs maybe for 165333-71-1

Shanghai Surseechem Co.,Ltd.

Contact:+86-21-61318535

Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
Luna Chemicals Co.,Ltd.

Contact:+86-570-4336358

Address:No.87 Building,Tianqian,Sidu Town
CGeneTech (Suzhou, China) Co., Ltd.

Contact:+86-512-62956962

Address:Room 101，Bld C11,218 Xinghu Rd.,Suzhou industrial Park
taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China
Tianjin Realet Chemical Technology Co.,Ltd.

website:http://www.realetchem.com

Contact:+86-022-58788819

Address:shuanggang industrial park

Relevant to this article

Doi:10.1039/jr9560000640
(1956)
Benzylidenecyanomethyl-1,3-benzazoles as 1-aza-1,3-butadienes

Doi:10.1248/cpb.42.1367
(1994)
Doi:10.1021/ja00977a052
(1967)
Chelating triarylgermyl anions as ligands in lanthanide chemistry: synthesis of Ln2 and the crystal structure of an unusual μ-(o-tolylene)digermane byproduct

Doi:10.1016/0022-328X(94)05296-N
(1995)
Synthesis of Optically Active α-Methylene γ-Butyrolactones and (+)-Mintlactone

Doi:10.1016/0040-4020(95)00236-2
(1995)
Doi:10.1021/j100851a061
(1968)

Article Doi