Stereospezifische Umlagerung von P-halogensubstituierten Phosphorylid-Komplexen in Phosphan-Komplexe

DOI: 10.1016/0022-328X(94)05240-C

Source and publish data:

Journal of Organometallic Chemistry p. 71 - 82 (1995)

Update date:2022-08-04

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Authors:

Fischer, Helmut

Schmid, Johann

Riede, Juergen

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Article abstract of DOI:10.1016/0022-328X(94)05240-C

At low temperatures the benzylidene complexes (CO)5W=C(R)H (1) add PPHCl2 at the carbene carbon to form the ylide complexes (CO)5W-C(R)H-PPhCl2 (3).These isomerize at room temperature to give the phosphine complexes (CO)5W-P(P

Full text of DOI:10.1016/0022-328X(94)05240-C

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