Experimental and theoretical analysis of the steric tolerance of the binding site of bacterioopsin with the use of side-chain methyl-shifted retinal analogs

DOI: 10.1021/ja00136a021

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Journal of the American Chemical Society p. 8220 - 8231 (1995)

Update date:2022-08-02

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Authors:

De Lera, Angel R.

Iglesias, Beatriz

Rodríguez, Jesús

Alvarez, Rosana

López, Susana

Villanueva, Xavier

Padrós, Esteve

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Article abstract of DOI:10.1021/ja00136a021

Four positional isomers of trans-retinal (1) differing in the location of the side-chain methyl groups have been prepared by a combination of Wittig and highly stereocontrolled Suzuki coupling reactions. The incubation of 9-demethyl-10-methylretinal (5) w

Full text of DOI:10.1021/ja00136a021

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