Substituent effects in the highly regioselective and diastereoselective ene reaction of singlet oxygen with chiral cyclohexadienes

DOI: 10.1021/ja00115a003

Source and publish data:

Journal of the American Chemical Society p. 2694 - 2697 (1995)

Update date:2022-08-03

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Authors:

Linker, Torsten

Fr?hlich, Lothar

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Article abstract of DOI:10.1021/ja00115a003

The photooxygenation of the cyclohexadienes 3 and 4, which are readily available through Birch reduction of 2-methylbenzoic acid (1), yielded only one regioisomeric hydroperoxide in a remarkable high diastereoselectivity. A strong directing effect on the

Full text of DOI:10.1021/ja00115a003

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