Synthesis of Aminophosphines Containing a Chiral Dinaphthoazepine Entity and their Use in Asymmetric Catalysis

DOI: 10.1007/BF00817258

Source and publish data:

Monatshefte fur Chemie p. 669 - 682 (1996)

Update date:2022-08-03

Topics:

Authors:

Wimmer, P.

Widhalm, M.

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Article abstract of DOI:10.1007/BF00817258

Three azaphospha ligands with a chiral dinaphthoazepine subunit were prepared and used in asymmetric carbon-carbon bond forming reactions.The nickel catalyzed Grignard cross coupling reaction of 1-phenylethyl magnesium chloride and vinyl bromide afforded

Full text of DOI:10.1007/BF00817258

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Product name:4-((2-Chloromethyl)-phenyl)-4H-dinaphth<2,1-c:1',2'-e>azepine

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