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112-27-6

Basic Information
CAS No.: 112-27-6
Name: Ethanol,2,2'-[1,2-ethanediylbis(oxy)]bis-
Molecular Structure:
Molecular Structure of 112-27-6 (Ethanol,2,2'-[1,2-ethanediylbis(oxy)]bis-)
Formula: C6H14O4
Molecular Weight: 150.17
Synonyms: NSC 60758;TEG;TEG(glycol);Trigen;Triglycol;Trigol;Triethyleneglycol (8CI);1,2-Bis(2-hydroxyethoxy)ethane;1,2-Di(b-hydroxyethoxy)ethane;1,8-Dihydroxy-3,6-dioxaoctane;2,2'-Ethylenedioxydiethanol;2-[2-(2-Hydroxyethoxy)ethoxy]ethanol;3,6-Dioxaoctane-1,8-diol;Glycol bis(hydroxyethyl) ether;Triethylene glycol;
EINECS: 203-953-2
Density: 1.124 g/cm3
Melting Point: -7 °C
Boiling Point: 288 °C at 760 mmHg
Flash Point: 165.6 °C
Solubility: 50 mg/mL at 20 °C in water
Appearance: clear liquid
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36
Transport Information:
PSA: 58.92000
LogP: -0.99580
Synthetic route
1447497-19-9

methyl 2-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-4-nitrobenzoate

A

1447497-21-3

2-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-4-nitrobenzoic acid

B

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
With methanol; water; sodium hydroxide for 2h; Reflux;A 72%
B n/a

triethylene glycol bromide

1447497-17-7

2,5-dihydroxy-4-nitrobenzoic acid methyl ester

A

1447497-20-2

2,5-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-4-nitrobenzoic acid

B

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
Stage #1: triethylene glycol bromide; methyl 2,5-dihydroxy-4-nitrobenzoate With potassium carbonate In acetone Inert atmosphere; Reflux;
Stage #2: With methanol; water; sodium hydroxide for 2h; Reflux;
A 50%
B n/a
75-21-8

oxirane

107-21-1

ethylene glycol

A

111-46-6

diethylene glycol

B

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
at 100℃;
75-21-8

oxirane

107-21-1

ethylene glycol

A

112-60-7

Tetraethylene glycol

B

111-46-6

diethylene glycol

C

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
at 130 - 210℃; unter Druck, 1 Mol Aethylenoxyd;
75-21-8

oxirane

107-21-1

ethylene glycol

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
at 100℃;
barium(II) oxide at 275℃; for 70h; Yield given;
75-21-8

oxirane

111-46-6

diethylene glycol

A

112-60-7

Tetraethylene glycol

B

4792-15-8

Pentaethylene glycol

C

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

75-21-8

oxirane

A

107-21-1

ethylene glycol

B

111-46-6

diethylene glycol

C

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
at 180 - 200℃; Hydrolysis;
With water at 100℃; pH=6; Product distribution / selectivity; Multiclave;
With water; CR11:H+2 at 100℃; pH=5; Product distribution / selectivity; Multiclave;
75-21-8

oxirane

A

111-46-6

diethylene glycol

B

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
With water at 160 - 200℃; under 11032.6 - 14710.2 Torr;
107-21-1

ethylene glycol

106-93-4

ethylene dibromide

A

112-60-7

Tetraethylene glycol

B

4792-15-8

Pentaethylene glycol

C

111-46-6

diethylene glycol

D

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
at 115 - 120℃; Produkt5: Hexaaethylenglykol;
107-21-1

ethylene glycol

106-93-4

ethylene dibromide

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
at 115 - 120℃;
68375-96-2

2-methyl-11-crown-4

A

75-07-0

acetaldehyde

B

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
With water; hydrogenchloride In 1,4-dioxane Rate constant; Equilibrium constant; Ambient temperature; effect of alkali and alkaline earth metal chlorides, concentrations of HCl and electrolyte;
77130-22-4

2,2-diphenyl-1,3,6,9-tetraoxacycloundecane

A

119-61-9

benzophenone

B

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
With hydrogenchloride In 1,4-dioxane; water at 30℃; Rate constant; Kinetics; Thermodynamic data; ΔH(excit.), ΔS(excit.), var. temp.;
107-21-1

ethylene glycol

A

123-91-1

1,4-dioxane

B

111-46-6

diethylene glycol

C

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
With carbon monoxide; Λ(+)-tris(pentane-2,5-dionato)ruthenium at 200℃; under 112509 Torr;
With carbon monoxide; Λ(+)-tris(pentane-2,5-dionato)ruthenium at 200℃; under 112509 Torr; Product distribution;

C6H14O4*Li(1+)

A

lithium cation

B

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
In acetonitrile at 25℃; Rate constant; Equilibrium constant; different concentrations;
107-21-1

ethylene glycol

A

123-91-1

1,4-dioxane

B

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
Multistep reaction;
107-07-3

2-chloro-ethanol

aqueous NaOH-solution

aqueous NaOH-solution

A

107-21-1

ethylene glycol

B

111-46-6

diethylene glycol

C

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

7553-56-2

iodine

111-46-6

diethylene glycol

A

112-60-7

Tetraethylene glycol

B

4792-15-8

Pentaethylene glycol

C

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
at 190℃;
107-21-1

ethylene glycol

A

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

B

diethylene glycol, tetraethylene glycol

diethylene glycol, tetraethylene glycol

Conditions
ConditionsYield
With sulfuric acid
75-21-8

oxirane

107-21-1

ethylene glycol

A

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

B

diethylene glycol, tetraethylene glycol

diethylene glycol, tetraethylene glycol

Conditions
ConditionsYield
With sulfuric acid at 90℃;
at 210℃; unter Druck;
111-46-6

diethylene glycol

A

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

B

tetraethylene glycol, pentaethylene glycol

tetraethylene glycol, pentaethylene glycol

Conditions
ConditionsYield
With iodine at 190℃;
75-21-8

oxirane

111-46-6

diethylene glycol

A

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

B

tetraethylene glycol, pentaethylene glycol

tetraethylene glycol, pentaethylene glycol

Conditions
ConditionsYield
at 193℃;
146669-11-6

2-(2-{[(dimethoxytrityl)oxy]ethoxy}ethoxy)ethanol

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
With sodium periodate In acetone at 20℃; for 16h;
862072-76-2

bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 2-[2-(2-{2-[2-(2-methoxyethoxy)ethoxy]acetoxy}ethoxy)ethoxy]ethyl ester

A

16024-58-1

2-[2-(2-methoxyethoxy)etoxy]acetic acid

B

27063-48-5, 34733-86-3, 37750-50-8, 117835-14-0, 143916-13-6

bicyclo[2.2.1]hept-2-ene-5-carbonyl chloride

C

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
With phosphate-buffered saline at 80℃; pH=7.4; Kinetics; Further Variations:; pH-values; Temperatures;
75-21-8

oxirane

75-56-9, 16033-71-9

methyloxirane

A

Reaxys ID: 15741318

Reaxys ID: 15741318

B

107-21-1

ethylene glycol

C

111-46-6

diethylene glycol

D

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
Stage #1: Pentaerythritol; methyloxirane With potassium hydroxide In water at 150℃; under 2250.23 - 3000.3 Torr; for 1.5h;
Stage #2: oxirane at 150℃; under 2250.23 - 3000.3 Torr; for 2.5h;
Stage #3: With acetic acid pH=~ 6; Product distribution / selectivity;
75-21-8

oxirane

124-38-9

carbon dioxide

A

96-49-1

[1,3]-dioxolan-2-one

B

107-21-1

ethylene glycol

C

111-46-6

diethylene glycol

D

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
With Polyglykol DME 500; water; potassium iodide at 200℃; for 2h; Product distribution / selectivity;
2615-15-8

pentaethylene glycol

A

64-18-6

formic acid

B

112-60-7

Tetraethylene glycol

C

4792-15-8

Pentaethylene glycol

D

107-21-1

ethylene glycol

E

64-19-7

acetic acid

F

111-46-6

diethylene glycol

G

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions
ConditionsYield
With titanium(IV) oxide In water for 24h; Concentration; UV-irradiation;
76-83-5

trityl chloride

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

133699-09-9

10,10,10-triphenyl-3,6,9-trioxadecan-1-ol

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 24h; Inert atmosphere;100%
With pyridine at 45℃; for 16h; Etherification;99%
With pyridine at 45℃;95%
98-59-9

p-toluenesulfonyl chloride

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

19249-03-7

triethylene glycol di-(p-toluenesulfonate)

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran for 24h;100%
With potassium hydroxide In dichloromethane at 0℃; for 3h;100%
Stage #1: 2,2'-[1,2-ethanediylbis(oxy)]bisethanol With sodium hydroxide In tetrahydrofuran; water at 0℃; for 1h;
Stage #2: p-toluenesulfonyl chloride In tetrahydrofuran; water at 20℃;
100%
18162-48-6

tert-butyldimethylsilyl chloride

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

201037-95-8

2-(2-(2-(tert-butyl-dimethyl-silanyloxy)-ethoxy)-ethoxy)-ethanol

Conditions
ConditionsYield
Stage #1: 2,2'-[1,2-ethanediylbis(oxy)]bisethanol With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 0.666667h;
Stage #2: tert-butyldimethylsilyl chloride In tetrahydrofuran; mineral oil at 20℃; for 23h;
100%
With pyridine; dmap at 20℃;84%
With dmap In dichloromethane at 0 - 20℃; for 4h;80.2%
38869-93-1

D,L-4,5-Dihydro-3-isocyanato-(3H)-thiophen-2-on

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

C11H19NO6S

Conditions
ConditionsYield
With dibutyltin(II) dilaurate In ethyl acetate at 65℃; for 4h; Schlenk technique; Inert atmosphere;100%

ethyl 2-bromo-4-(4-(trifluoromethyl)phenyl)thiazole-5-carboxylate

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

2-(2-(2-(2-hydroxyethoxy)ethoxy)ethoxy)-4-(4-(trifluoromethyl)phenyl)thiazole-5-carboxylic acid

Conditions
ConditionsYield
Stage #1: 2,2'-[1,2-ethanediylbis(oxy)]bisethanol With sodium hydride In mineral oil at 0 - 20℃; for 0.166667h; Inert atmosphere;
Stage #2: ethyl 2-bromo-4-(4-(trifluoromethyl)phenyl)thiazole-5-carboxylate In mineral oil at 60℃; for 5h; Inert atmosphere;
100%
886577-76-0

2-isocyanato-2-methylpropane-1,3-diyl diacrylate

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

2-(((2-(2-(2-hydroxyethoxy)ethoxy)ethoxy)carbonyl)amino)-2-methylpropane-1,3-diyl diacrylate

Conditions
ConditionsYield
With dibutyltin dilaurate; 4-methoxy-phenol In diethyl ether at 40℃; for 12h; Flow reactor;99.7%
With dibutyltin dilaurate; 4-methoxy-phenol In tetrahydrofuran at 75℃; for 5h;
30674-80-7

2-Isocyanatoethyl methacrylate

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

13-hydroxy-4-oxo-5,8,11-trioxa-3-azatridecyl methacrylate

Conditions
ConditionsYield
With dibutyltin dilaurate; 4-methoxy-phenol In diethyl ether at 40℃; for 12h; Flow reactor;99.5%
With dibutyltin dilaurate; 4-methoxy-phenol In tetrahydrofuran at 75℃; for 5h;
107023-60-9

2-(2-methacryloyloxyethyloxy)ethyl isocyanate

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

16-hydroxy-7-oxo-3,8,11,14-tetraoxa-6-azahexadecyl methacrylate

Conditions
ConditionsYield
With dibutyltin dilaurate; 4-methoxy-phenol In diethyl ether at 40℃; for 12h; Flow reactor;99.3%
With dibutyltin dilaurate; 4-methoxy-phenol In tetrahydrofuran at 75℃; for 5h;
100-44-7

benzyl chloride

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

55489-58-2

triethylene glycol monobenzyl ether

Conditions
ConditionsYield
Stage #1: 2,2'-[1,2-ethanediylbis(oxy)]bisethanol With tetrabutylammomium bromide; sodium hydride In tetrahydrofuran; mineral oil for 0.333333h;
Stage #2: benzyl chloride In tetrahydrofuran; mineral oil for 24h; Reflux; Inert atmosphere;
99%
Stage #1: 2,2'-[1,2-ethanediylbis(oxy)]bisethanol With sodium hydroxide In water at 20℃; for 0.5h;
Stage #2: benzyl chloride In water at 100℃; for 24h;
80.7%
With sodium hydroxide at 100℃; for 24h;73%
98-59-9

p-toluenesulfonyl chloride

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

77544-68-4

8-tosyloxy-3,6-dioxaoctanol

Conditions
ConditionsYield
at 0 - 20℃; Alkaline conditions;99%
With sodium hydroxide96%
With triethylamine In dichloromethane at 0 - 20℃; for 18h; Inert atmosphere;96%
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

123-91-1

1,4-dioxane

Conditions
ConditionsYield
With copper(ll) bromide at 175℃; for 6h; Inert atmosphere; Sealed tube;99%
With Sulfate; zirconium(IV) oxide at 180℃; for 1.41667h; cyclodehydration;
814-68-6

acryloyl chloride

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

1680-21-3

2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 1h;99%
Stage #1: 2,2'-[1,2-ethanediylbis(oxy)]bisethanol With triethylamine In dichloromethane at 0℃; Inert atmosphere;
Stage #2: acryloyl chloride In dichloromethane at 0 - 20℃; for 1h; Inert atmosphere;
57%
56706-10-6

4,4,13,13-tetraethoxy-3,14-dioxa-8,9-dithia-4,13-disilahexadecane

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

1036978-39-8

bis[tri(hydroxytriethyleneoxy)silylpropyl] disulfide

Conditions
ConditionsYield
With sodium ethanolate In ethanol at 150℃; under 20 Torr; for 2h; Under reduced presure;99%
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

618-51-9

3-Iodobenzoic acid

C20H20I2O6

Conditions
ConditionsYield
With dmap; diisopropyl-carbodiimide In dichloromethane99%
150-76-5

4-methoxy-phenol

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

141788-62-7

1,10-bis(4-methoxyphenyl)-1,4,7,10-tetraoxaundecane

Conditions
ConditionsYield
With dicyclohexyl-carbodiimide In acetonitrile at 85℃; for 30h; Temperature; Time;98.46%
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

352546-86-2

triethylene glycol bis(dichlorophosphate)

Conditions
ConditionsYield
With trichlorophosphate In dichloromethane at 20℃;98%
With trichlorophosphate
577794-93-5

1,11-bis(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-3,6,9-trioxaundecane-1,11-dione

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

1,4,7,10,15,18,21-heptaoxacyclopentacosane-11,13,23,25-tetraone

Conditions
ConditionsYield
In chlorobenzene Heating;98%
623-42-7

butanoic acid methyl ester

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

26962-26-5

triethylene glycol di-n-butyrate

Conditions
ConditionsYield
With potassium carbonate at 100 - 110℃;98%
554-12-1

propanoic acid methyl ester

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

141-34-4

triethylene glycol dipropionate

Conditions
ConditionsYield
With potassium carbonate at 90 - 95℃;98%
105-54-4

butanoic acid ethyl ester

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

26962-26-5

triethylene glycol di-n-butyrate

Conditions
ConditionsYield
With potassium carbonate at 115 - 140℃;98%
624-24-8

methyl valerate

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

97766-66-0

triethylene glycol di-n-pentanoate

Conditions
ConditionsYield
With potassium carbonate at 126 - 165℃; under 750.075 Torr;98%
65-85-0

benzoic acid

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

120-56-9

triethylene glycol dibenzoate

Conditions
ConditionsYield
With toluene-4-sulfonic acid at 180 - 210℃;97%
With H2SO4/TiO2-La2O3-solid acid catalyst In 5,5-dimethyl-1,3-cyclohexadiene at 185 - 190℃; for 11h;92.6%
With toluene-4-sulfonic acid; xylene
With tin(IV) oxide In 5,5-dimethyl-1,3-cyclohexadiene at 180℃;
1115-15-7

divinyl sulfoxide

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

C34H66O16S4

Conditions
ConditionsYield
With sodium hydroxide at 65℃; for 5h;97%
124-63-0

methanesulfonyl chloride

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

80322-82-3

triethyleneglycol dimesylate

Conditions
ConditionsYield
With triethylamine In dichloromethane97%
Stage #1: 2,2'-[1,2-ethanediylbis(oxy)]bisethanol With triethylamine In dichloromethane at 0℃; for 0.166667h;
Stage #2: methanesulfonyl chloride In dichloromethane at 20℃; for 12h;
92.9%
With triethylamine In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere;86%
39148-58-8

4-benzoylbenzoyl chloride

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

1,8-Bis(4-benzoylbenzoyloxy)-3,6-dioxaoctane

Conditions
ConditionsYield
With pyridine In dichloromethane Ambient temperature;97%
935-79-5

cis-1,2,3,6-tetrahydrophthalic anhydride

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

888485-47-0

C22H30O10

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 9h;97%
149-57-5

2-Ethylhexanoic acid

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

94-28-0

triethylene glycol bis(2-ethylhexanoate)

Conditions
ConditionsYield
With titanium(IV) isopropylate at 220℃; under 225.023 - 450.045 Torr; for 3h; Reagent/catalyst; Pressure; Time; Concentration; pH-value;97%
With pyrographite at 225℃; under 300.03 - 675.068 Torr; for 14.5h; Product distribution / selectivity;
With pyrographite at 225℃; under 300.03 - 675.068 Torr; for 14.5h; Product distribution / selectivity;
696-62-8

para-iodoanisole

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

167567-16-0

2-[2-[2-(4-methoxyphenoxy)ethoxy]ethoxy]ethanol

Conditions
ConditionsYield
With potassium carbonate; copper(l) chloride at 130℃; for 24h; Inert atmosphere;97%
142-61-0

Hexanoyl chloride

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

25176-75-4

triethylene glycol di-n-hexanoate

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane for 3h;96%
1663-39-4

tert-Butyl acrylate

112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

186020-66-6

3-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-propionic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: 2,2'-[1,2-ethanediylbis(oxy)]bisethanol With sodium In tetrahydrofuran at 20℃;
Stage #2: tert-Butyl acrylate In tetrahydrofuran at 20℃; for 20h;
Stage #3: With hydrogenchloride; water In tetrahydrofuran
96%
With sodium In tetrahydrofuran at 20℃; for 24h;95.5%
With sodium In tetrahydrofuran for 20h;86%
  • Triethylene glycol Manufacturer/High quality/Best price/In stock

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  • High quality 2,2'-(Ethylenedioxy)Diethanol supplier in China

  • Casno:

    112-27-6

    High quality 2,2'-(Ethylenedioxy)Diethanol supplier in China

    Min.Order: 0 Metric Ton

    FOB Price:  USD $ 0.0-0.0/Metric Ton

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    Appearance: Colourless liquid Chemical Name: Triethylene glycol Molecular Formula: C6H14O4 Melting point : -7.2℃ Boiling point: 285℃ CAS No.:112-27-6 Appearance:Colorless liquid Storage:Preserve in well-closed, light-resistant and airti

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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    Shanghai Upbio Tech Co.,Ltd (Former Onchem (China)Co.,Ltd) is a comprehensive manufacturer and an international distribution of chemicals throughout the world, The predecessor of

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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    Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer

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    112-27-6

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    112-27-6

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    Business Type:Lab/Research institutions

    Tel:+86-571-85134551

    Address:No. 206 Zhen Hua Road, Hangzhou 310030, Zhejiang, China

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  • Triethylene glycolCAS NO.: 112-27-6

  • Casno:

    112-27-6

    Triethylene glycolCAS NO.: 112-27-6

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Specification

The IUPAC name of Triethylene glycol is 2-[2-(2-hydroxyethoxy)ethoxy]ethanol. With the CAS registry number 112-27-6, it is also named as 2,2'-(1,2-Ethanediylbis(oxy))bisethanol. The product's categories are ethylene glycol; ethylene glycols; ethylene glycols & monofunctional ethylene glycols. It is colorless, odorless, viscous and hygroscopic liquid which is miscible with water and ethanol, slightly soluble in ether, almost insoluble in petroleum ether. It is slightly toxic and combustible. Additionally, Triethylene glycol is non-corrosive to metal and do not react with the majority plastic and rubber. When not use, it should sealed in the container which must placed in the cool and dry aera.

The other characteristics of Triethylene glycol can be summarized as: 
(1)ACD/BCF (pH 5.5): 1; (2)ACD/BCF (pH 7.4): 1; (3)ACD/KOC (pH 5.5): 2.29; (4)ACD/KOC (pH 7.4): 2.29; (5)#H bond acceptors: 4; (6)#H bond donors: 2; (7)#Freely Rotating Bonds: 9; (8)Index of Refraction: 1.45; (9)Molar Refractivity: 36.4 cm3; (10)Molar Volume: 135.3 cm3; (11)Polarizability: 14.43×10-24 cm3; (12)Surface Tension: 41.6 dyne/cm; (13)Enthalpy of Vaporization: 61.18 kJ/mol; (14)Vapour Pressure: 0.000268 mmHg at 25 °C; (15)Rotatable Bond Count: 7; (16)Exact Mass: 150.089209; (17)MonoIsotopic Mass: 150.089209; (18)Topological Polar Surface Area: 58.9; (19)Heavy Atom Count: 10.

Preparation of Triethylene glycol: 
It is obtained, with diethylene glycol, as a by-product in the manufacture of ethylene glycol from hydrolysis of ethylene oxide.
6CH2CH2O + 3H2O → HOCH2CH2OH + HOCH2CH2OCH2CH2OH + HOCH2CH2OCH2CH2OCH2CH2OH
It is separated from the ethylene glycol and diethylene glycol by vacuum distillation.

Uses of Triethylene glycol:
It is not only used as a plasticizer for vinyl, but also used in Air-Sanitizer products. When aerosolized, it acts as a disinfectant. Additionally, Triethylene glycol is also used as liquid desiccants for natural gas and in air conditioning systems. Furthermore, it is an additive for hydraulic fluids and brake fluids and used as a base for "smoke machine" fluid in the entertainment industry. 

Safety information of Triethylene glycol:
When you are using Triethylene glycol, please be cautious about it as the following:It is irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing.

People can use the following data to convert to the molecule structure. 
(1)Canonical SMILES: C(COCCOCCO)O
(2)InChI: InChI=1S/C6H14O4/c7-1-3-9-5-6-10-4-2-8/h7-8H,1-6H2
(3)InChIKey: ZIBGPFATKBEMQZ-UHFFFAOYSA-N

The following are the toxicity data of Triethylene glycol:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LD50 intravenous > 4500mg/kg (4500mg/kg)   Arzneimittel-Forschung. Drug Research. Vol. 18, Pg. 1536, 1968.
 
guinea pig LD50 intravenous 10600mg/kg (10600mg/kg)   Arzneimittel-Forschung. Drug Research. Vol. 18, Pg. 1536, 1968.
 
guinea pig LD50 oral 7900mg/kg (7900mg/kg)   Journal of Industrial Hygiene and Toxicology. Vol. 28, Pg. 40, 1946.
human LDLo oral 5gm/kg (5000mg/kg)   Food and Cosmetics Toxicology. Vol. 17, Pg. 913, 1979.
mammal (species unspecified) LD50 oral 8150mg/kg (8150mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(4), Pg. 86, 1974.
mouse LD50 intraperitoneal 8141mg/kg (8141mg/kg) LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA

BLOOD: CHANGES IN SPLEEN

KIDNEY, URETER, AND BLADDER: CHANGES IN BOTH TUBULES AND GLOMERULI
Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 6, Pg. 342, 1947.
mouse LD50 intravenous 6500mg/kg (6500mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 65, Pg. 89, 1939.
mouse LD50 subcutaneous 8750mg/kg (8750mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 65, Pg. 89, 1939.
mouse LDLo oral 18500mg/kg (18500mg/kg)   Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 1186, 1966.
rabbit LD50 intravenous 1900mg/kg (1900mg/kg)   Arzneimittel-Forschung. Drug Research. Vol. 18, Pg. 1536, 1968.
 
rabbit LD50 oral 8400mg/kg (8400mg/kg)   Journal of Industrial Hygiene and Toxicology. Vol. 28, Pg. 40, 1946.
rabbit LD50 skin > 20mL/kg (20mL/kg)   "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 731, 1969.
rat LD50 intravenous 11700mg/kg (11700mg/kg)   Arzneimittel-Forschung. Drug Research. Vol. 18, Pg. 1536, 1968.
 
rat LD50 oral 17gm/kg (17000mg/kg)   Journal of Industrial Hygiene and Toxicology. Vol. 28, Pg. 40, 1946.
rat LDLo intramuscular 8400mg/kg (8400mg/kg)   Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 29, Pg. 5, 1940.