Selective alternate derivatization of the hexaphenylbenzene framework through a thermodynamically controlled halogen dance

DOI: 10.1021/ol500041j

Source and publish data:

Organic Letters p. 1024 - 1027 (2014)

Update date:2022-07-30

Topics:

Authors:

Kojima, Tatsuo

Hiraoka, Shuichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ol500041j

We report a practical synthetic protocol and mechanistic details for the selective alternate derivatization of the hexaphenylbenzene (HPB) framework through a thermodynamically controlled halogen dance. The stability of the alternately trilithiated specie

Full text of DOI:10.1021/ol500041j

Products guided by the article

Product name:1-bromo-4-(2-(4-(trifluoromethyl)phenyl)ethynyl)benzene

Cas No:167858-54-0

R&D Labs maybe for 167858-54-0

Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)

Contact:+86-512-69598882

Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Shanghai Longjin Metallic Material Co., Ltd.

website:http://www.shlongjin.cn/

Contact:021-56517503,56502257

Address:No.16, Lane 555, Chengyin Road, Shanghai
taicang liyuan chemical co,.ltd

website:http://www.tcliyuanchem.com/productse.php

Contact:86-512-53539583

Address:Room 804,Huaxu Building,No.95,Renmin South Road,Taicang city,Jiangsu Province,China
Shijiazhuang Sdyano Fine Chemical Co., Ltd

Contact:+86-311-89830448

Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone

Relevant to this article

A novel and simple method to prepare γ-hydroxy-α,β-(E)-alkenoic esters from γ-keto-alkynoic esters

Doi:10.1016/S0040-4039(02)02602-3
(2003)
Remarkably mild and efficient catalytic Sakurai reaction of N-alkoxycarbonylamino sulfones with allyltrimethylsilane using indium(III) chloride

Doi:10.1016/j.tetlet.2007.09.077
(2007)
Vanadium-catalyzed selenide oxidation with in situ [2,3] sigmatropic rearrangement (SOS reaction): Scope and asymmetric applications

Doi:10.1039/b316502g
(2004)
Highly Ligand Efficient and Selective N-2-(Thioethyl)picolinamide Histone Deacetylase Inhibitors Inspired by the Natural Product PsammaplinA

Doi:10.1002/cmdc.201200450
(2013)
Hydrogen-bonding-promoted oxidative addition and regioselective arylation of olefins with aryl chlorides

Doi:10.1021/ja1081926
(2010)
The vicarious nucleophilic substitution of hydrogen and related reactions in nitrobenzoxazoles

Doi:10.1016/0040-4020(95)00351-8
(1995)

Article Doi