Synthesis p. 964 - 968 (1995)
Update date:2022-08-05
Topics:
Schank
Beck
Pistorius
Rapold
Acyloxylation of different types of enol ethers (derived from aldehydes and ketones) by dimethyl peroxydicarbonate (DPDC) results in either addition to the double bond or in a formal replacement of an allylic hydrogen by a methoxycarbonyloxy group forming vicinal oxygenated hydrocarbons. 1,3-Oxygenated products via monoacyloxylation could not be observed. The results are compared with copper(I)-catalyzed acyloxylations of 1-methoxycyclohex-1-ene (1a) by means of tert-butyl peroxycarboxylates 2a, b.
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(2017)Doi:10.1021/ja970614c
(1997)Doi:10.1007/BF00950997
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(2019)Doi:10.1016/S0040-4039(00)78243-8
(1994)
