Acyloxylation of 1-methoxycyclohex-1-ene and other enol ethers with dimethyl peroxydicarbonate

DOI: 10.1055/s-1995-4026

Source and publish data:

Synthesis p. 964 - 968 (1995)

Update date:2022-08-05

Topics:

Authors:

Schank Schank

Beck Beck

Pistorius

Rapold Rapold

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1995-4026

Acyloxylation of different types of enol ethers (derived from aldehydes and ketones) by dimethyl peroxydicarbonate (DPDC) results in either addition to the double bond or in a formal replacement of an allylic hydrogen by a methoxycarbonyloxy group forming vicinal oxygenated hydrocarbons. 1,3-Oxygenated products via monoacyloxylation could not be observed. The results are compared with copper(I)-catalyzed acyloxylations of 1-methoxycyclohex-1-ene (1a) by means of tert-butyl peroxycarboxylates 2a, b.

Full text of DOI:10.1055/s-1995-4026

Products guided by the article

Product name:1-methoxy-cyclohex-1-en-6-yl methyl carbonate

Cas No:171512-51-9

R&D Labs maybe for 171512-51-9

Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian
NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
Taizhou Chenyi chemical co. LTD,

Contact:13736652831

Address:NO.273 SHANGHAI SOUTH STREET,LUQIAO DISTRICT,ZHEJIANG PROVINCE,CHINA.
Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China

Relevant to this article

Glycomimetic selectin inhibitors: (α-D-mannopyranosyloxy)methylbiphenyls

Doi:10.1016/0960-894X(96)00071-6
(1996)
Tetraphenylantimony aroxides Ph₄SbOAr (Ar = C₆H₄C₆H₇, C₆H₂(Br₂-2,6)(tert-Bu-4), C₆H₃(NO₂)₂-2,4, C₆H₂(Br₂-2,6)(NO₂-4)): Synthesis and structure

Doi:10.1134/S0036023617030147
(2017)
Total synthesis of the cyclic biphenyl ether peptides K-13 and OF494-III via S(N)Ar macrocyclizations of peptidyl ruthenium π-arene complexes

Doi:10.1021/ja970614c
(1997)
Doi:10.1007/BF00950997
()
A Dogma in Doubt: Hydrolysis of Equatorial Ligands of Pt^IV Complexes under Physiological Conditions

Doi:10.1002/anie.201900682
(2019)
Oligodeoxynucleotide probes with multiple labels linked to the 4'-position of thymidine monomers: Excellent duplex stability and detection sensitivity

Doi:10.1016/S0040-4039(00)78243-8
(1994)

Article Doi