Sodium tetraphenylborate as a phenylating agent for gold(I) complexes

DOI: 10.1016/0022-328X(95)05589-H

Source and publish data:

Journal of Organometallic Chemistry p. 47 - 52 (1995)

Update date:2022-08-04

Topics:

Authors:

Sladek, Alexander

Hofreiter, Stefan

Paul, Martin

Schmidbaur, Hubert

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(95)05589-H

Phenylgold(I) has been prepared from tris<gold(I)>oxonium tetrafluoroborate and sodium tetraphenylborate in ethanol at ambient temperature.The compound is aslo available from chlorogold(I) and phenyllthium in tetrahydrofuran. 1,4-Bis(diphenylphosphinomethyl>benzene has been generated from the chloro complex 1,4-<(ClAu)Ph2PCH2>2C6H4 either with silver oxide and sodium tetraphenylborate or with phenyllithium.The compounds have been identified by their analytical and spectroscopic data, and their structures have been determined by single-crystal X-ray diffraction studies.Keywords: Phenylgold(I) Complexes; Tetraphenylborates as phenylating agents; Phenylation

Full text of DOI:10.1016/0022-328X(95)05589-H

Products guided by the article

Product name:1,4-bis([phenylgold(I)](diphenyl)phosphinomethyl)benzene

Cas No:172532-10-4

R&D Labs maybe for 172532-10-4

Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun
Hubei New Desheng Technology Co., Ltd

website:http://www.whdsbio.cn

Contact:+86-15071057538

Address:C8-2-2, Optical Valley United Technology City, Gedian Development Zone, Ezhou , City Hubei, China.
Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai

Relevant to this article

Catalysis with platinum-group alkylamido complexes. The active palladium amide in catalytic aryl halide aminations as deduced from kinetic data and independent generation

Doi:10.1021/om960188o
(1996)
Alpha-phenyl-alpha(2,3-cyclohexenyl) acetic acid derivatives as potential antispasmodics.

Doi:10.1002/jps.2600570406
(1968)
Efficient synthesis of α-branched purine-based acyclic nucleosides: Scopes and limitations of the method

Doi:10.3390/molecules25184307
(2020)
Synthesis of a Symmetric Multivalent Molecule containing four Carbohydrate Substituents

Doi:10.1007/BF00811012
(1995)
Toward the development of a general chiral auxiliary. 3. Design and evaluation of a novel chiral bicyclic lactam for asymmetric aldol condensations: Evidence for the importance of dipole alignment in the transition state

Doi:10.1021/ja00154a053
(1995)
Elemental carbon chain bridging two iron centers: Syntheses and spectroscopic properties of donor-acceptor [Fe]-C₄-[Fe] complexes isolated in two different oxidation states. X-ray crystal structure of [Cp*(dppe)Fe-C₄-Fe(CO)₂Cp*]

Doi:10.1021/om970730o
(1997)

Article Doi