Sodium tetraphenylborate as a phenylating agent for gold(I) complexes

DOI: 10.1016/0022-328X(95)05589-H

Source and publish data:

Journal of Organometallic Chemistry p. 47 - 52 (1995)

Update date:2022-08-04

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Authors:

Sladek, Alexander

Hofreiter, Stefan

Paul, Martin

Schmidbaur, Hubert

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Article abstract of DOI:10.1016/0022-328X(95)05589-H

Phenylgold(I) has been prepared from tris<gold(I)>oxonium tetrafluoroborate and sodium tetraphenylborate in ethanol at ambient temperature.The compound is aslo available from chlorogold(I) and phenyllthium in tetrahydrofuran. 1,4-Bis(diphenylphosphinomethyl>benzene has been generated from the chloro complex 1,4-<(ClAu)Ph2PCH2>2C6H4 either with silver oxide and sodium tetraphenylborate or with phenyllithium.The compounds have been identified by their analytical and spectroscopic data, and their structures have been determined by single-crystal X-ray diffraction studies.Keywords: Phenylgold(I) Complexes; Tetraphenylborates as phenylating agents; Phenylation

Full text of DOI:10.1016/0022-328X(95)05589-H

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