Stereoselective cycloadditions of chiral acyl-nitroso compounds; Palladium(0) catalyzed allylic displacement with concomitant loss of the chiral auxiliary

DOI: 10.1016/0040-4039(95)01527-2

Source and publish data:

Tetrahedron Letters p. 7541 - 7544 (1995)

Update date:2022-08-03

Topics:

Authors:

Muxworthy, James P.

Wilkinson, James A.

Procter, Garry

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Article abstract of DOI:10.1016/0040-4039(95)01527-2

The methylated diacetate 4, derived from the readily available hydroxamic acid 1, undergoes Pd⁰ catalyzed nucleophilic allylic displacement under conditions which also result in the removal of the chiral auxiliary and its replacement with an easily removed acetyl group.

Full text of DOI:10.1016/0040-4039(95)01527-2

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