Journal of the Chemical Society, Dalton Transactions p. 3447 - 3454 (1995)
Update date:2022-08-05
Topics:
Beer, Paul D.
Drew, Michael G. B.
Hodacova, Jana
Stokes, Sally E.
A new macrocyclic amide-substituted cobaltocenium receptor 1.1'-<(ethylenedioxy)bis(ethyleneaminocarbonyl)>cobaltocenium hexafluorophosphate 2 has been prepared and its single-crystal X-ray structure determined.Proton NMR anion co-ordination studies revealed that 2 and other new acyclic cobaltocenium derivatives complex chloride and bromide anions with 1:1 stoichiometry.Comparative stability constant evaluations imply that the macrocyclic receptor 2 forms halide complexes of greatest thermodynamic stability, suggestive of a 'macrocyclic anion effect'.Cyclic voltammetric investigations showed the cobaltocenium receptors to electrochemically recognise halide anions.
Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）
Contact:+86-533-2975022
Address:No.99 Shanquan Road, Zhangdian District
Contact:86-25-51817806
Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china
Naturalin Bio-Resource Co., Ltd
website:http://www.naturalin.com
Contact:+86-0731-84430651
Address:B1-402, Lu-Valley Enterprise Square.No.27 Wenxuan Road. Lu-Valley Hi-Tech District.
Meryer (Shanghai) Chemical Technology Co., Ltd.
website:http://www.meryer.com/cn/index/
Contact:+86-755-86170518
Address:Minhang,Shanghai, China
Hongyi Import & Export CO.,LTD
Contact:86-13319649499
Address:Nanzheng Neighborhood Commitees, Chongwen Office, Yongding District
Doi:10.1016/0040-4020(63)85035-8
(1963)Doi:10.1002/chem.201403735
(2014)Doi:10.1139/v85-136
(1985)Doi:10.1039/c7md00656j
(2018)Doi:10.1016/S0040-4039(00)98420-X
(1985)Doi:10.1016/j.phytochem.2012.08.001
(2012)
