Tetrahedron Letters p. 8591 - 8594 (1995)
Update date:2022-08-03
Topics:
Maddaluno, Jacques
Gaonac'h, Odile
Gallic, Yann Le
Duhamel, Lucette
γ-Functionalized α,β-unsaturated dimethyl acetals undergo a methanol δ-elimination upon basic treatment, leading to 1,4-disubstituted 1,3-dienes in good yields and, in several cases, with high stereocontrol of the newly formed double bonds.
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