Double stereodifferentiation in the Lewis acid promoted crotylation of (S)-2-alkoxypropanal with chiral β-alkyl (E)-crotylsilanes

DOI: 10.1016/0040-4039(95)01895-O

Source and publish data:

Tetrahedron Letters p. 8727 - 8730 (1995)

Update date:2022-08-05

Topics:

Authors:

Jain Jain

Jain, Nareshkumar F.

Cirillo Cirillo

Cirillo, Pier F.

Pelletier

Pelletier, Roberta

Panek Panek

Panek, James S.

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Article abstract of DOI:10.1016/0040-4039(95)01895-O

The sense and level of 1,2-asymmetric induction have been evaluated in the Lewis acid promoted addition of (E)-crotylsilanes (S)-1 and (R)-2 to (S)-2-alkoxypropanal 3 and 7. These aldehydes are substituted at the α-position with benzyloxy (OBn) to reinfor

Full text of DOI:10.1016/0040-4039(95)01895-O

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