Diastereomerically pure pyrrolidin-2-ones by intramolecular Michael reaction. Synthesis of both (S)- and (R)-3-pyrrolidineacetic acid

DOI: 10.1016/0957-4166(95)00423-8

Source and publish data:

Tetrahedron Asymmetry p. 79 - 88 (1996)

Update date:2022-09-26

Topics:

Authors:

Galeazzi, Roberta

Geremia, Silvano

Mobbili, Giovanna

Orena, Mario

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Article abstract of DOI:10.1016/0957-4166(95)00423-8

By intramolecular conjugate addition of their derived enolates, the amides 5 and 6 gave diastereomeric mixtures of pyrrolidin-2-ones 10,11 and 12,13, in good yield and 80:20 d.r. After chromatographic separation, the configuration of pure diastereomers wa

Full text of DOI:10.1016/0957-4166(95)00423-8

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