Zeitschrift fur Anorganische und Allgemeine Chemie p. 562 - 570 (1996)
Update date:2022-09-26
Topics:
Severin, Kay
Koch, Daniela
Polborn, Kurt
Beck, Wolfgang
The reactions of the hydrido complexes RuHCl(CO)· (PPh3)3, RuH2(PPh3)4 and IrH3(PPh3)3 with N-acyl-α-aminocarboxylates give the carboxylate complexes RuCl(O2CCHRNHCOR′)(CO)(PPh3)2 (1-3), RuH(O2CCHRNHCOR′)(PPh3)3 (4-6) and IrH2(O2CCH2NHCOPh)(PPh3)3 (7). The structure of RuCl· (O2CCHNHCOPh)(CO)(PPh3)2 (1) has been determined by x-ray diffraction. The triphenylphosphine complexes MBr· (O2CCH2NHCOR)(CO)2(PPh3)2 (M = Mo, W) (8-12) and Mo(O2CCHRNHCOR′)2(CO)2(PPH 3)2 (13-17) are formed from MBr2(CO)2(PPh3)2 (M = Mo, W) with one or two equivalents of N-acyl-a-aminoacidates, respectively. Johann Ambrosius Barth 1996.
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