Helvetica Chimica Acta p. 1627 - 1638 (1997)
Update date:2022-08-02
Topics:
You, Shaochun
Chai, Shengyong
Schwarz, Nadine
Neuenschwander, Markus
Pentalene dimers 2 and 3 are easily available in moderate yields by CuCl2-induced oxidative coupling of dilithium-pentalenediide (5) (Scheme 1).On the other hand, NBS bromination of 1,5-dihydropentalene (4) or of 1,2-dihydropentalene (8) gives unstable 1-bromo-1,2-dihydropentalene (9), while subsequent in-situ elimination with Et3N exclusively gives syn-cis-pentalene dimer 2 in moderale yields (Scheme3).NMR-Spectroscopic evidence for compounds 2. 3. and 9 is presented, and mechanistic alternatives for the formation of pentalene dimers 2 and 3 are discussed.
View MoreZhengzhou Yuanli Biological Technology Co., Ltd.
Contact:+86-371-67897870/67897895
Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Shandong Jiulong Hisince Pharmaceutical Co.,Ltd.
Contact:+86-15853188990
Address:Huadian Pioneer Park, Huadian Township, Qihe County, Dezhou City, Shandong, P.R.China
Hangzhou Ocean Chemical Co., Ltd.
website:http://www.hzoceanchem.com
Contact:+86-571-88025872, 28272092, 28272096
Address:Room 623 ,Building No 1 , COFCO Radius Commercial Center Xiwen Road, Xiacheng District, Hangzhou, Zhejiang Province, China
Beijing Wisdom Chemicals Co., Ltd.
Contact:+86-10-52350335
Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Shanghai SMEC Trading Co., Ltd.
website:http://www.shanghaismec.com
Contact:+86-21-68811293
Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
Doi:10.1002/hlca.19960790210
(1996)Doi:10.1002/ardp.19673000608
(1967)Doi:10.1039/b208115f
(2002)Doi:10.1016/j.polymer.2010.11.055
(2011)Doi:10.1021/acs.orglett.9b03054
(2019)Doi:10.1016/S0022-1139(96)03452-5
(1996)
