Journal of the Chemical Society, Dalton Transactions p. 2011 - 2016 (1996)
Update date:2022-08-03
Topics:
Field, Leslie D.
George, Adrian V.
Hockless, David C. R.
Purches, Graham R.
White, Allan H.
Complexes of the form [Ru(C≡CR′)2(L-L)2] [L-L = R2PCH2CH2PR2; R = Me (dmpe) or Et (depe); R′ = But, Ph, 4-HC≡CC6H4,4-MeOC6H4 or 3,5-(F3C)2C6H3] were prepared by reaction of[RuCl2(L-L)2] or [RuH2(L-L)2] with terminal acetylenes in methanol solution. The spectroscopic data indicate that the acetylide groups adopt a trans stereochemistry across the metal centre. The crystal structure of [Ru(C≡CPh)2(dmpe)2] was determined.
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