Bulletin of the Chemical Society of Japan p. 1409 - 1417 (2000)
Update date:2022-08-03
Topics:
Hirabayashi, Kazunori
Ando, Jun-Ichi
Kawashima, Jun
Nishihara, Yasushi
Mori, Atsunori
Hiyama, Tamejiro
The reaction of dimethyl(phenyl)silanol with butyl acrylate in the presence of a stoichiometric amount of Pd(OAc)2 or by a combined use of 0.1 molar amount of Pd(OAc)2 and Cu(OAc)2/LiOAc (molar ratio 3/2) gave butyl cinnamate in 76% or 57% yield, respectively. The similar reaction with tributyl(phenyl)tin also proceeded in 77% yield. The organotin compound was shown to react faster than the sitanol, although the tin reagent sometimes induced undesirable homocoupling, while the reaction with silanol did not give such by-product.
View MoreContact:021-50278900
Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
Contact:+44 (0)161 367 9441
Address:
Shanghai doly chemical Co.,Ltd
Contact:+86-21-34716221
Address:No.328,WuHe Roard,MinHang,ShangHai China
Shandong Yaroma Perfumery Co., Ltd.
Contact:+86- 531- 88024598
Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Shanghai shibo Chemical Co., Ltd
Contact:+86-021-60753516
Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Doi:10.1016/0022-2860(95)09164-5
(1996)Doi:10.1002/ejoc.201300704
(2013)Doi:10.1021/jm500860w
(2015)Doi:10.1021/jo00370a006
(1986)Doi:10.1021/jm00317a068
(1967)Doi:10.1016/j.bioorg.2015.04.004
(2015)
