Chemical and Pharmaceutical Bulletin p. 1282 - 1284 (1996)
Update date:2022-07-29
Topics:
Kiguchi, Toshiko
Shirakawa, Mitsuko
Ninomiya, Ichiya
Naito, Takeaki
A combination of 1,3-dipolar cycloaddition of Z-nitrone (2) to the chiral dipolarophile (3) and subsequent ring transformation of the resulting adducts (4 and 6) to piperidinol (17) has provided a new practical synthesis of 2,3,6-trisubstituted piperidine alkaloid, (+)-azimic acid (1).
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(1996)Doi:10.1021/jo202253q
(2012)
