Rhodium(III)-mediated cycloaddition of alkynes: Reactivity of [Cp*Rh(η2-NO3)(OTf)] bearing two labile ligands

DOI: 10.1016/S0022-328X(03)00451-0

Source and publish data:

Journal of Organometallic Chemistry p. 102 - 107 (2003)

Update date:2022-08-03

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Authors:

Han, Won Seok

Lee, Soon W.

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Article abstract of DOI:10.1016/S0022-328X(03)00451-0

[Cp*Rh(η²-NO₃)(OTf)] (1) mediated cyclodimerization or cyclotrimerization of alkynes and alkynyl esters. In addition, compound 1 reacted with propargyl halides to give triply halide-bridged dinuclear compounds, [Cp*Rh(μ₂-X

Full text of DOI:10.1016/S0022-328X(03)00451-0

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