Synthesis of benzocycloheptenones by 1,3-dipolar additions of 2-(1,3-benzodioxol-5-ylmethyl)-4-hydroxy-3-methoxycarbonylisoquinolin-2-ium chloride with dipolarophiles

DOI: 10.1039/p19960002005

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2005 - 2008 (1996)

Update date:2022-09-26

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Authors:

Edmunds, Jeremy J.

Cheng, Xue-Min

Tobias, Brian

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Article abstract of DOI:10.1039/p19960002005

The addition of thionyl chloride to dihydroisoquinolines affords isoquinolinium chlorides which are readily converted to the corresponding ylides upon treatment with sodium hydrogen carbonate. These ylides undergo facile 1,3-dipolar additions with dimethy

Full text of DOI:10.1039/p19960002005

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