Tetrahedron Letters p. 1995 - 1998 (1993)
Update date:2022-07-30
Topics:
Raposo, Cesar
Crego, Mercedes
Partearroyo, Anselmo
Mussons, Ma. Luisa
Caballero, Ma. Cruz
Moran, Joaquin R.
Dibutylmalonic acid receptors have been designed to optimize their catalytic decarboxylative activity in the presence of isoquinoline.A phosphonamide group is responsible for the catalytic activity, probably because its tetrahedral geometry is complementary to the transition state. Key words: Molecular recognition, Malonic acids, Decarboxylation, Hydrogen bond, Catalytic activity
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