Dibutylmalonic Acid Receptors with Decarboxylative Activity

DOI: 10.1016/S0040-4039(00)91985-3

Source and publish data:

Tetrahedron Letters p. 1995 - 1998 (1993)

Update date:2022-07-30

Topics:

Authors:

Raposo, Cesar

Crego, Mercedes

Partearroyo, Anselmo

Mussons, Ma. Luisa

Caballero, Ma. Cruz

Moran, Joaquin R.

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Article abstract of DOI:10.1016/S0040-4039(00)91985-3

Dibutylmalonic acid receptors have been designed to optimize their catalytic decarboxylative activity in the presence of isoquinoline.A phosphonamide group is responsible for the catalytic activity, probably because its tetrahedral geometry is complementary to the transition state. Key words: Molecular recognition, Malonic acids, Decarboxylation, Hydrogen bond, Catalytic activity

Full text of DOI:10.1016/S0040-4039(00)91985-3

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