Mercury-Photosensitized Sulfination, Hydrosulfination, and Carbonylation of Hydrocarbons: Alkane and Alkene Conversion to Sulfonic Acids, Ketones, and Aldehydes

DOI: 10.1021/jo00019a006

Source and publish data:

Journal of Organic Chemistry p. 5503 - 5510 (1991)

Update date:2022-08-03

Topics:

Authors:

Ferguson, Richard R.

Crabtree, Robert H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00019a006

Mercury-photosensitized sulfination of alkanes, RH, with SO2 forms sulfinic acids (RSOOH) and sulfinate esters (RSOOR) in high conversion and yield; oxidation of the mixture produces RSO2OH in high yield.Mercury-photosensitized hydrosulfination of alkenes with H2 and SO2 gives RSO2OH after oxidative workup.Mercury-photosensitized carbonylation of alkanes with CO gives RCHO and R2CO.

Full text of DOI:10.1021/jo00019a006

Products guided by the article

Product name:4-Heptanesulfonic acid

Cas No:183278-21-9

R&D Labs maybe for 183278-21-9

Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)

Contact:010-52876516

Address:tongzhoubeiyuan
Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
Shanghai Yuking Water Soluble Material Tech Co., Ltd

Contact:86-21-68286299

Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
Zhangjiagang Jianing Import & Export Co.,Ltd.

Contact:086-512-55379012 13913607595

Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Hebei Think-Do Environment Co., Ltd

website:http://www.thinkdo-environment.com

Contact:0311-86510809-

Address:No 6, Shilian Middle Street, Circular Chemical Industry Park

Relevant to this article

Thermal Ring Contraction of Oxygenated Pyrazines to Imidazoles via Diazoxepins

Doi:10.1039/c39830000399
(1983)
Substituent effects in solvolysis of 1,1-diphenylethyl p-nitrobenzoates. Symmetrically disubstituted and monosubstituted systems

Doi:10.1002/poc.484
(2002)
Chemistry of 2,4-Diaminothiopyranylium Iodides Syntheses of α,β,γ,δ-Unsaturated Thiocarboxamides

Doi:10.1007/BF00798954
(1983)
Synthesis of some quinazoline-2(1H),4(3H)-dione derivatives

Doi:10.1002/jccs.200500022
(2005)
Discovery of Potent Non-Nucleoside Inhibitors of Dengue Viral RNA-Dependent RNA Polymerase from a Fragment Hit Using Structure-Based Drug Design

Doi:10.1021/acs.jmedchem.6b00143
(2016)
Synthesis of a novel series of 6,6′-disubstituted 4,4′-bipyrimidines by radical anion coupling: New π-accepting ligands for coordination chemistry

Doi:10.1002/ejoc.200500335
(2005)

Article Doi