
Tetrahedron p. 14437 - 14458 (1996)
Update date:2022-08-03
Topics:
Hart, David J.
Merriman, Gregory H.
Young, David G. J.
A synthesis of chrysomycin substructure 44 is described in which a Ramberg-Backlund reaction plays a key role. Electrochemical oxidation of 44 provided 45, and unsuccessful attempts to convert 45 to chrysomycin B (2) are presented.
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