Synthesis of C-aryl glycosides related to the chrysomycins

DOI: 10.1016/0040-4020(96)00876-9

Source and publish data:

Tetrahedron p. 14437 - 14458 (1996)

Update date:2022-08-03

Topics:

Authors:

Hart, David J.

Merriman, Gregory H.

Young, David G. J.

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Article abstract of DOI:10.1016/0040-4020(96)00876-9

A synthesis of chrysomycin substructure 44 is described in which a Ramberg-Backlund reaction plays a key role. Electrochemical oxidation of 44 provided 45, and unsuccessful attempts to convert 45 to chrysomycin B (2) are presented.

Full text of DOI:10.1016/0040-4020(96)00876-9

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