Solvatothermal synthesis and crystal structure of (Ph4P)[(VO2)4(CH3CO 2)4cl]

DOI: 10.1016/s0020-1693(96)05325-x

Source and publish data:

Inorganica Chimica Acta p. 435 - 438 (1996)

Update date:2022-09-26

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Authors:

Salta, José

Zubieta, Jon

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Article abstract of DOI:10.1016/s0020-1693(96)05325-x

The solvatothermal reaction of (Ph₄P)[VO₂Cl₂] with acetic acid in methylene chloride at 110°C for 48 h yields bright red crystals of (Ph₄P)[(VO₂)₄(CH₃CO ₂)₄Cl] (1) in 20% yield. The structure of the anion of 1 consists of a tetrakis(μ-acetato-μ-oxo-oxovanadium) crown with a chloride guest anion occupying the hollow formed by the edge-sharing of the four {VO₅} square pyramids. Crystal data: C₃₂H₃₂O₁₆PClV₄, tetragonal I4₁/a, a = 15.969(2), c = 29.020(5) A?, V = 7400(1) A?³, Z = 8.

Full text of DOI:10.1016/s0020-1693(96)05325-x

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Product name:(C₆H₅)4P⁽¹⁺⁾*(VO₂)4(CH₃CO₂)4*Cl^(1-)=[(C₆H₅)4P][(VO₂)4(CH₃CO₂)4Cl]

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