
Tetrahedron Asymmetry p. 3535 - 3544 (1996)
Update date:2022-08-02
Topics:
Acena, Jose Luis
Arjona, Odon
Plumet, Joaquin
A new synthesis of (+)-pinitol 9 has been developed starting from the 7-oxanorbornenic sulfone (+)-5, prepared in enantiomerically pure form by resolution of the sulfonyl-7-oxanorbornanol 4. These precursors are available from the Diels-Alder adduct of furan and trans-1,2-bis-(phenylsulfonyl)-ethylene.
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