Mechanism of anomerization of cyclohexyl 2-deoxy-3,4,6-tri-O-methyl-2-(N-methylacetamido)-α- and β-D-hexopyranosides under reductive-cleavage conditions

Article abstract of DOI:10.1016/S0008-6215(96)00251-0

The fully methylated cyclohexyl glycosides of 2-acetamido-2-deoxy-α- and β-D-hexopyranoses having the gluco, manno, and galacto configurations were each subjected to reductive-cleavage conditions using one of three promoters, namely trimethylsilyl, triflu