Highly diastereoselective synthesis of 11β,17β-diaryl-18a-homo-19-nor steroids

DOI: 10.1002/prac.19973390164

Source and publish data:

Journal fur Praktische Chemie - Chemiker-Zeitung p. 365 - 370 (1997)

Update date:2022-09-26

Topics:

Authors:

Ottow, Eckhard

Cleve, Arwed

Neef, Guenter

Schwede, Wolfgang

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Article abstract of DOI:10.1002/prac.19973390164

In a highly diastereoselective fashion novel 11β, 17β-diaryl steroids 17 and 18 were synthesized via Birch-type reduction [1] of styrylic precursors 11 and 15. Both precursors were readily available by Suzuki-type coupling reactions [2] of aromatic boroni

Full text of DOI:10.1002/prac.19973390164

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Product name:11-(4-methoxyphenyl)-18a-homoestra-5,9⁽¹¹⁾-diene-3,17-dione cyclic bis(1,2-ethanediyl acetal)

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