Novel Type of the Favorskii Rearrangement Combined with Aldol Reaction Leading to γ-Butyrolactone Derivatives

DOI: 10.1246/bcsj.60.1067

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1067 - 1070 (1987)

Update date:2022-08-05

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Authors:

Sakai, Takashi

Yamawaki, Akitoshi

Katayama, Tsuyoshi

Okada, Hiroshi

Utaka, Masanori

Takeda, Akira

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Article abstract of DOI:10.1246/bcsj.60.1067

Reaction of aromatic aldehydes or hetero-aromatic aldehydes with 3-chloro-3-methyl-2-butanone in ethanolic KOH at room temperature gave 3,3-dimethyl-5-aryltetrahydro-2-furanone as a major product.The reaction can be tentatively explained by the combination of Favorskii rearrangement and aldol reaction.

Full text of DOI:10.1246/bcsj.60.1067

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