Synthesis and structure of a dimeric peralkylated hexaaminobenzene: Hexakis(dimethylamino)hexamethyl-hexaaza[63](1,3,5)cyclophane

Article abstract of DOI:10.1002/anie.199706211

Increasing reorganization energy slows intramolecular electron transfer (ET) in 1, a compound thus well-suited for studying the kinetics of ET processes. A suprisingly smooth, threefold nucleophilic aromatic substitution reaction is the key step in the sy