Tetrahedron Letters p. 3435 - 3438 (1997)
Update date:2022-07-29
Topics:
Fukuda, Tsutomu
Katsuki, Tsutomu
Allyl aryl sulfides and diazoacetic acid esters react in the presence of optically active Co(III)-salen complex (4) with good enantioselectivity, to give the [2,3]sigmatropic rearrangement products, 2-arylthio-3-aryl-4-pentenoic acid esters, via the corresponding S-ylides.
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