Co(III)-salen catalyzed carbenoid reaction: Stereoselective [2,3]sigmatropic rearrangement of S-ylides derived from allyl aryl sulfides

DOI: 10.1016/S0040-4039(97)00639-4

Source and publish data:

Tetrahedron Letters p. 3435 - 3438 (1997)

Update date:2022-07-29

Topics:

Authors:

Fukuda, Tsutomu

Katsuki, Tsutomu

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Article abstract of DOI:10.1016/S0040-4039(97)00639-4

Allyl aryl sulfides and diazoacetic acid esters react in the presence of optically active Co(III)-salen complex (4) with good enantioselectivity, to give the [2,3]sigmatropic rearrangement products, 2-arylthio-3-aryl-4-pentenoic acid esters, via the corresponding S-ylides.

Full text of DOI:10.1016/S0040-4039(97)00639-4

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