
Journal of the Chemical Society. Chemical communications p. 1699 - 1700 (1993)
Update date:2022-07-29
Topics:
Aitken, R. Alan
Drysdale, Martin J.
Ryan, Bruce M.
Flash vacuum pyrolysis of α-alkanesulfinyl phosphorus ylides results mainly in extrusion of Ph3P to give thioesters, presumably by 1,2-oxygen transfer in the initially formed sulfinyl carbenes; for α-arenesulfinyl ylides loss of Ph3PO to give additional products is also observed.
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