An iminophosphine-palladium catalyst for cross-coupling of aryl halides with organostannanes

Article abstract of DOI:10.1016/S0040-4039(97)00747-8

A palladium complex bearing iminophosphine ligand, N-(2- diphenylphosphinobenzylidene)-2-phenylethylamine (1), was found to be more catalytically active than others for the cross-coupling of various types of aryl halides with alkynyl-, alkenyl- and arylstannanes to give the corresponding coupling products in high yields.