Tetrahedron Letters p. 4627 - 4630 (1997)
Update date:2022-08-02
Topics:
Kodama, Mitsuaki
Yoshio, Suzuyo
Tabata, Tomoki
Deguchi, Yuka
Sekiya, Yasumi
Fukuyama, Yoshiyasu
(3R,6S,7R,18R,19S)-, (3R,6S,7R,18R,19R)-, and (3R,6S,7R,18S,19R)-Quassiols A were synthesized enantioselectively by using baker's yeast reduction and asymmetric dihydroxylation, but their optical properties were not identical to that of natural quassiol A. Stereostructure of natural quassiol A was proposed.
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