Tetrahedron Letters p. 5433 - 5436 (1997)
Update date:2022-08-04
Topics:
Schultz, Arthur G.
Pettus, Liping
Birch reduction-alkylation of the chiral 2-(trimethylsilyl)benzamide 4 provides 1,4-cyclohexadienes 5b-5e with diastereomer ratios of >100:1. The conversions of 5b-5e to the 4,4-disubstituted-2-cyclohexen-1-ones 8b-8e are described.
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