Asymmetric Synthesis of Unsaturated Pipecolic Acid Derivatives

DOI: 10.1055/s-1997-5752

Source and publish data:

Synlett p. 799 - 800 (1997)

Update date:2022-08-03

Topics:

Authors:

Agami, Claude

Bihan, Dominique

Morgentin, Rémy

Puchot-Kadouri, Cathy

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Article abstract of DOI:10.1055/s-1997-5752

Two enantiopure pipecolic acid derivatives having an olefinic moiety were synthesized from an intramolecular addition of allyl silanes on an iminium double bond. The iminium moiety was generated via a reaction of chiral β-amino alcohols with glyoxal.

Full text of DOI:10.1055/s-1997-5752

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