Tetrahedron Letters p. 6759 - 6762 (1997)
Update date:2022-08-03
Topics:
Pohmakotr, Manat
Thisayukta, Jirakorn
α-Chloro-α-(phenylthio)cyclopropane and α-acetoxy-α-(phenylthio)cyclopropane were found to react with the silyl enol ethers of some ketones in the presence of Lewis acid in dichloromethane to provide α-(phenylthio)cyclopropyl ketones, which were subjected to reduction with Ra-Ni to give the corresponding α-cyclopropyl ketones.
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