Tetrahedron Letters p. 7333 - 7336 (1997)
Update date:2022-08-05
Topics:
White, James D.
Holoboski, Mark A.
Green, Neal J.
An asymmetric synthesis of the C14-C26 segment of rhizoxin is described in which the three stereogenic centers are derived from a γ-lactone; stannylcupration-methylation of a terminal alkyne is used to generate an (E)-iodoalkene for Stille coupling with a dienylstannane that produces the conjugated (E,E,E)-triene unit of rhizoxin.
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Doi:10.1080/00397911.2016.1205196
(2016)Doi:10.1021/ja01599a051
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(1997)Doi:10.1016/0022-1902(74)80653-6
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(1968)Doi:10.1021/ja01022a052
(1968)
