Tetrahedron Letters p. 7333 - 7336 (1997)
Update date:2022-08-05
Topics:
White, James D.
Holoboski, Mark A.
Green, Neal J.
An asymmetric synthesis of the C14-C26 segment of rhizoxin is described in which the three stereogenic centers are derived from a γ-lactone; stannylcupration-methylation of a terminal alkyne is used to generate an (E)-iodoalkene for Stille coupling with a dienylstannane that produces the conjugated (E,E,E)-triene unit of rhizoxin.
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