Tetrahedron Letters p. 1419 - 1422 (1999)
Update date:2022-09-26
Topics:
Malpass
Cox
A synthetic route to the epibatidine analogue endo-5-(6-chloro-3- pyridyl)-2-azabicyclo[2.2.1]heptane and the corresponding endo-6- isomer is described, starting from a readily-available 2-azabicyclo[2.2.1]hept-5-ene derivative. Both the exo-5- and exo-6- compounds are also shown to be accessible from the same substrate using reductive Heck chemistry.
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