10.1002/anie.201802656
Angewandte Chemie International Edition
COMMUNICATION
conversion of Pd(II) to Pd(0) has been observed in light-induced
Heck reactions.[32,33]
approach in other bimetallic reactions is currently ongoing in our
laboratories.
Acknowledgements
The project leading to this application has received funding from
the European Union’s Horizon 2020 research and innovation
program under the Marie Sklodowska-Curie grant agreement No
641861. We also acknowledge financial support from the Spanish
MINECO (CTQ2017-84825-R). M.V.G. thanks MINECO for
participation in the Ramón y Cajal program (RYC2007-14768).
Keywords: Photocatalysis • Visible light • Negishi coupling •
C(sp3)–C(sp2) coupling • Flow Chemistry
Figure 4. Effect of light in the degradation of an intermediate signal and in the
acceleration of the formation of dimer 28. Green arrows mark when the light was
turned on and orange arrows when the light was turned off.
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